Facile functionalization of a metal carbon bond by O-atom transfer.
نویسندگان
چکیده
The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 128 28 شماره
صفحات -
تاریخ انتشار 2006